An effective and accessible cell configuration for testing rechargeable zinc-based alkaline batteries

نویسندگان

چکیده

Rechargeable aqueous zinc-air batteries have received much attention due to their intrinsic safety, high theoretical volumetric energy density (6134 Wh/L), and low cost. However, zinc anodes suffer from severe hydrogen evolution reaction (HER) in alkaline electrolytes, which are kinetically favorable for air cathodes. Through an electrochemical cell–gas chromatography setup, we quantitatively identified that 99% of the capacity loss on anode was caused by HER. Most previous research has focused material design suppress HER, while less been paid device. Here demonstrate testing device apparent effect HER electrolytes. Stainless-steel coin cells, as common devices used laboratories, accelerate synergistic effects galvanic corrosion a activity. We designed effective accessible cell configuration zinc-based batteries, minimizes demonstrates higher Coulombic efficiency longer cycling life than stainless-steel cells. Minimized self-discharge Zn were visualized through operando optical microscopy. Specifically, Ni–Zn battery with our achieved stable long-term 816 cycles compared ~100 cell. The shown here can be directly or modified future batteries.

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ژورنال

عنوان ژورنال: Journal of Power Sources

سال: 2021

ISSN: ['1873-2755', '0378-7753']

DOI: https://doi.org/10.1016/j.jpowsour.2021.229547